研究業績

投稿論文(2010年以降)

α-Arylation of Alkylamines with Sulfonylarenes through a Radical Chain Mechanism

Ikeda, Y.; Ueno, R.; Akai, Y.; Shirakawa, E.

Chem. Commun2018, 54, 10471–10474.

 

Electron-Catalyzed Cross-Coupling of Arylboron Compounds with Aryl Iodides

Okura, K.; Teranishi, T.; Yoshida, Y.; Shirakawa, E.

Angew. Chem., Int. Ed2018, 57, 7186–7190.

Highlighted in Synfacts 201814, 0852.

 

Electron-Catalyzed Coupling of Magnesium Amides with Aryl Iodides

Kiriyama, K.; Okura, K.; Tamakuni, F.; Shirakawa, E.

Chem. Eur. J2018, 24, 4519–4522.

 

tert-Butoxide-Promoted Coupling of Aryl Iodides with Arenes Using Di-tert-butyl Hyponitrite as an Initiator

Kiriyama, K.; Shirakawa, E.

Chem. Lett. 2017, 46, 1757–1759.

cl-170814figc

 

tert-Butoxy-Radical-Promoted α-Arylation of Alkylamines with Aryl Halides

Ueno, R.; Ikeda Y.; Shirakawa, E.

Eur. J. Org. Chem. 2017, 4188–4193.

ejoc201700548-toc-0001

 

Single Electron Transfer-Induced Coupling of Alkynylzinc Reagents with Aryl and Alkenyl Iodides

Okura, K.; Kawashima, H.; Tamakuni, F.; Nishida, N.; Shirakawa, E.

Chem. Commun. 201652, 14019–14022.

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Single-Electron-Transfer-Induced Coupling of Alkylzinc Reagents with Aryl Iodides

Okura, K.; Shirakawa, E.

Eur. J. Org. Chem. 2016, 3043–3046.

ejoc201600367-toc-0001

 

Reduction of Aryl Halides into Arenes with 2-Propanol Promoted by a Substoichiometric Amount of a tert-Butoxy Radical Source

Ueno, R.; Shimizu, T.; Shirakawa, E.

Synlett 2016, 27, 741–744.

i_r0932_ga_10-1055_s-0035-1561342

 

Base-Promoted Dehydrogenative Coupling of Benzene Derivatives with Amides or Ethers.

Ueno, R.; Shirakawa, E.

Org. Biomol. Chem. 2014, 12, 7469–7473.

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An Improved Procedure for the Single Electron Transfer-Induced Grignard Cross-Coupling Reaction.
Shirakawa, E.; Okura, K.; Uchiyama, N.; Murakami, T.; Hayashi, T.
Chem. Lett. 2014, 43, 922–924.
cl-140155figc
Single-Electron-Transfer-Induced Coupling of Arylzinc Reagents with Aryl and Alkenyl Halides.
Shirakawa, E.; Tamakuni, F.; Kusano, E.; Uchiyama, N.; Konagaya, W.; Watabe, R.; Hayashi, T.
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Single Electron Transfer-Induced Cross-Coupling Reaction of Alkenyl Halides with Aryl Grignard Reagents.

Shirakawa, E.; Watabe, R.; Murakami, T.; Hayashi, T.

Chem. Commun. 2013, 49, 5219–5221.

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Indium-Catalyzed Annulation of 3-Aryl- and 3-Heteroarylindoles with Propargyl Ethers: Synthesis and Photoluminescent Properties of Aryl- and Heteroaryl[c]carbazoles.

Nagase, Y.; Shirai, H.; Kaneko, M.; Shirakawa, E.; Tsuchimoto, T.

Org. Biomol. Chem. 2013, 1456–1459.

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Copper-Catalyzed Oxidative C–C, C–O, and C–N Bond Forming Reactions of Arylboronic Acids.

Shirakawa, E.; Nishikawa, R.; Uchiyama, N.; Hata, I.; Hayashi, T.

Chem. Lett. 2013, 42, 269–271.

cl-121174figc

Single Electron Transfer-Induced Grignard Cross-Coupling Involving Ion Radicals as Exclusive Intermediates.

Uchiyama, N.; Shirakawa, E.; Hayashi, T.

Chem. Commun. 2013, 49, 364–366.

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Ruthenium-Catalyzed Transformation of Aryl and Alkenyl Triflates to Halides.

Imazaki, Y.; Shirakawa, E.; Ueno, R.; Hayashi, T.

J. Am. Chem. Soc. 2012, 134, 14760–14763.

 

ja-2012-07771d_0006

 

 

Iron–Copper Cooperative Catalysis in the Reactions of Alkyl Grignard Reagents: Exchange Reaction with Alkenes and Carbometalation of Alkynes.

Shirakawa, E.; Ikeda, D.; Masui, S.; Yoshida, M.; Hayashi, T.

J. Am. Chem. Soc. 2012, 134, 272–279.

ja-2011-06745w_0021

 

 

Cross-Coupling of Aryl Grignard Reagents with Aryl Iodides and Bromides through SRN1 Pathway.

Shirakawa, E.; Hayashi, Y.; Itoh, K.; Watabe, R.; Uchiyama, N.; Konagaya, W.; Masui, S.; Hayashi, T.

Angew. Chem., Int. Ed. 2012, 51, 218–221.

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Ruthenium-Catalyzed Reaction of Alkenyl Triflates with Zinc Thiolates.

Imazaki, Y.; Shirakawa, E.; Hayashi, T.

Tetrahedron 2011, 67, 10212–10215.

1-s2.0-S0040402011015298-fx1

 

 

Iron-Catalyzed Oxidative Coupling of Arylboronic Acids with Benzene Derivatives through Homolytic Aromatic Substitution Mechanism.

Uchiyama, N.; Shirakawa, E.; Nishikawa, R.; Hayashi, T.

Chem. Commun. 2011, 47, 11671–11673.

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Iron-Catalyzed Oxidative Coupling of Alkylamines with Arenes, Nitroalkanes, and 1,3-Dicarbonyl Compounds.

Shirakawa, E.; Yoneda, T. Moriya, K.; Ota, K.; Uchiyama, N.; Nishikawa, R.; Hayashi, T.

Chem. Lett. 2011, 40, 1041–1043.

cl-110599figc

Iron-Catalyzed Aryl- and Alkenyllithiation of Alkynes and Its Application to Benzosilole Synthesis

Shirakawa, E.; Masui, S.; Narui, R.; Watabe, R.; Ikeda, D.; Hayashi, T.

Chem. Commun. 2011, 47, 9714–9716.

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Mizoroki–Heck Type Reaction Mediated by Potassium tert-Butoxide.

Shirakawa, E.; Zhang, X.; Hayashi, T.

Angew. Chem. Int. Ed. 2011, 50, 4671–4674.

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Iron-Catalyzed Oxidative Coupling of Alkylamides with Arenes through Oxidation of Alkylamides Followed by Friedel–Crafts Alkylation.

Shirakawa, E.; Uchiyama, N.; Hayashi, T.

J. Org. Chem. 2011, 76, 25–34.

jo-2010-02217m_0002

 

 

tert-Butoxide-Mediated Arylation of Benzene with Aryl Halides in the Presence of a Catalytic

1,10-Phenanthroline Derivative.

Shirakawa, E.; Itoh, K.; Higashino, T.; Hayashi, T

J. Am. Chem. Soc. 2010, 132, 15537–15539.

ja-2010-080822_0004

 

 

総説・総合論文

電子触媒クロスカップリング反応

白川英二

ファルマシア, 2017, 53, 875–880.

 

電子一つを触媒とするハロゲン化アリールのカップリング反応

白川英二

有合化, 2013, 71, 526–534.

 

Transition-Metal-Free Coupling Reactions of Aryl Halides.

Shirakawa, E.; Hayashi, T.

Chem. Lett. 2012, 41, 130–134.

 

電子1個を触媒とするカップリング反応 —いかに遷移金属と同じように電子を操るか

白川英二

化学(化学同人),2011, 66, No. 12, 47–21.

 

遷移金属触媒を用いないハロゲン化アリールのカップリング反応

白川英二

Organometallic News, 2016, No. 3, 98–103.

 

 

著書

「ウォーレン有機化学」第2版(上)・(下)

Clayton, J.; Greeves, N.; Warren, S.; Wothers, P. 著, 野依良治, 奥山 格, 柴崎正勝, 檜山爲次郎 監訳, 白川英二 他 訳

東京化学同人: 東京, 2015.

 

 

「有機合成化学」

檜山爲次郎, 大嶌幸一郎 編著, 丸岡啓二, 高井和彦, 松原誠二郎, 野崎京子, 白川英二, 忍久保洋 著

東京化学同人: 東京, 2012.

 

 

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