Paper on the synthesis of one-handed o-oligophenylene-stacked molecules consisting of planar chiral [2.2]paracyclophane was published in Chem. Commun. Helicity of o-oligophenylenes was controlled by planar chirality of a [2.2]paracyclophane unit. It is the first example that one-handed helical o-oligophenylenes emit CPL (|glum| value > 0.01).
“Synthesis and Characterizations of One-handed Helical Oligo(o-phenylene)s: Control of Axial Chirality by the Planar Chiral [2.2]Paracyclophane”
Yanagawa. A.; Inoue, R.; Morisaki, Y.
Chem. Commun. 2024, 60, 1468-1471.
DOI: 10.1039/D3CC05000A
